Product Name :
2,8,9-Triisopropyl-2,5,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane (CAS 175845-21-3)
Synonym :
[2,5,8,9-Tetraaza-1-phosphabicyclo[3.3.3]undecane-2,8,9-tris(1-methylethyl)]
Application :
2,8,9-Triisopropyl-2,5,8,9-tetraaza-1-phosphabicyclo[3,3,3]undecane is A catalyst and a deprotonation agent.
CAS:
175845-21-3
Purity:
Molecular Weight:
300.42
Formula :
C15H33N4P
Physical state:
Liquid
solubility :
Shipping Condition :
Store at room temperature
Melting point:
SMILES:
CC(C)N1CCN2CCN(P1N(CC2)C(C)C)C(C)C
References:
:An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen. 2375424-00-1 web | Liu, T., et al. 2013. Nat Chem. Price of 2-Chloro-5-methoxypyridin-4-amine 5: 228-233. PMID: 23422565Incorporation of Pendant Bases into Rh(diphosphine)2 Complexes: Synthesis, Thermodynamic Studies, And Catalytic CO2 Hydrogenation Activity of [Rh(P2N2)2](+) Complexes. | Lilio, AM., et al. 2015. J Am Chem Soc. 137: 8251-60. PMID: 26042557Photocatalytic Reduction of Carbon Dioxide to CO and HCO2H Using fac-Mn(CN)(bpy)(CO)3. | Cheung, PL., et al. 2016. Inorg Chem. 55: 3192-8. PMID: 26996527Organocatalyst-assisted Ar-18F bond formation: a universal procedure for direct aromatic radiofluorination. | Jakobsson, JE., et al. 2017. Chem Commun (Camb). 53: 12906-12909. PMID: 29143838The Reactivity of Mercapto Groups against Boron Hydrides in Pincer Ligated Nickel Mercapto Complexes. | Zhang, J., et al. 2018. Chem Asian J. 13: 3231-3238. PMID: 30129168Evaluating the impacts of amino acids in the second and outer coordination spheres of Rh-bis(diphosphine) complexes for CO2 hydrogenation. | Walsh, AP., et al. 2019. Faraday Discuss. 215: 123-140. PMID: 30993272Enhanced carbon dioxide hydrogenation facilitated by catalytic quantities of bicarbonate and other inorganic salts | Drake, J. L., Manna, C. M., & Byers, J. A. 2013. Organometallics. 32(23): 6891-6894.One-pot sequential reactions for the synthesis of versatile 11 C-labeled olefin frameworks | Takashima, M., Kato, K., Ogawa, M., & Magata, Y. 2013. RSC advances. 3(44): 21275-21279.The influence of the second and outer coordination spheres on Rh (diphosphine) 2 CO2 hydrogenation catalysts. | Bays, J. T., Priyadarshani, N., Jeletic, M. S., Hulley, E. B., Miller, D. L., Linehan, J. C., & Shaw, W. J. 2014. ACS Catalysis. 4(10): 3663-3670.A cobalt hydride catalyst for the hydrogenation of CO2: pathways for catalysis and deactivation | Jeletic, M. S., Helm, M. L., Hulley, E. B., Mock, M. T., Appel, A. M., & Linehan, J. C. 2014. ACS Catalysis. 4(10): 3755-3762.Simple ligand modifications with pendent OH groups dramatically impact the activity and selectivity of ruthenium catalysts for transfer hydrogenation: the importance of alkali metals | Moore, C. M., Bark, B., & Szymczak, N. K. 2016. ACS Catalysis. 6(3): 1981-1990.Catalytic hydrogenation of CO 2 at a structurally rigidified cobalt center. | Choi, J., & Lee, Y. 2020. Inorganic Chemistry Frontiers. 7(9): 1845-1850.A nickel (II) complex of 2, 6-pyridinedicarboxylic acid ion, an efficient electro-catalyst for both hydrogen evolution and oxidation. | Du, J., Yang, H., Wang, C. L., & Zhan, S. Z. 2021. Molecular Catalysis. 516: 111947.
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