Product Name :
2,6-Dimethylphenyl isocyanide (CAS 2769-71-3)
Synonym :
vic.-m-Xylyl isocyanide
Application :
CAS:
2769-71-3
Purity:
Molecular Weight:
131.17
Formula :
C9H9N
Physical state:
Solid
solubility :
Shipping Condition :
Store at 4° C
Melting point:
72-76° C
SMILES:
CC1=C(C(=CC=C1)C)[N+]#[C-]
References:
:Isocyanide binding to the copper(I) centers of the catalytic core of peptidylglycine monooxygenase (PHMcc). Methyl 5-bromo-2,4-dimethylbenzoate web | Rhames, FC., et al. 2001. J Biol Inorg Chem. 6: 567-77. 3,4-Diethylhexane-3,4-diol web PMID: 11472020Reactions of the Dirhenium(II) Complexes Re(2)X(4)(dppm)(2) (X = Cl, Br; dppm = Ph(2)PCH(2)PPh(2)) with Isocyanides. 10.(1) Synthesis and Characterization of the Complex [Re(2)Br(3)(&mgr;-dppm)(2)(CO)(2)(CNXyl)]O(3)SCF(3) and Several Isomeric Forms of [Re(2)Br(3)(&mgr;-dppm)(2)(CO)(CNXyl)(2)]Y (Y = PF(6), O(3)SCF(3)). | Wu, W., et al. 1996. Inorg Chem. 35: 5484-5491. PMID: 11666734Copper(I)/S(8) reversible reactions leading to an end-on bound dicopper(II) disulfide complex: nucleophilic reactivity and analogies to copper-dioxygen chemistry. | Maiti, D., et al. 2007. J Am Chem Soc. 129: 8882-92. PMID: 17592845Carbon-nitrogen bond formation in the reaction between tetrakis(dimethylamido)molybdenum(IV) and 2,6-dimethylphenyl isocyanide. Preparation and characterization of the first homoleptic metallaamidine complex: Mo(.eta.2-Me2NC:NC6H3Me3-2,6)4. | Chisholm, MH., et al. 1986. J Am Chem Soc. 108: 7860-1. PMID: 22283313Effect of organic vapors on Au, Ag, and Au-Ag alloy nanoparticle films with adsorbed 2,6-dimethylphenyl isocyanide. | Kim, K., et al. 2013. J Colloid Interface Sci. 411: 194-7. PMID: 24054162Steric and Electronic Influence of Aryl Isocyanides on the Properties of Iridium(III) Cyclometalates. | Maity, A., et al. 2016. Inorg Chem. 55: 2299-308. PMID: 26905022Addition of Isocyanides to Tetramesityldigermene: A Comparison of the Reactivity between Surface and Molecular Digermenes. | Tashkandi, NY., et al. 2016. Chemistry. 22: 14006-14012. PMID: 27529452Oxygen Atom Transfer and Intramolecular Nitrene Transfer in a Rhenium beta -Diketiminate Complex. | Lohrey, TD., et al. 2016. Inorg Chem. 55: 11993-12000. PMID: 27934320The Diverse Reactivity of Disilenes Toward Isocyanides. | Tashkandi, NY., et al. 2019. Angew Chem Int Ed Engl. 58: 3167-3172. PMID: 30225855Crystal structure and DFT analyses of a pentacoordinated PCP pincer nickel(II) complex. | Subramaniyan, V., et al. 2019. Acta Crystallogr C Struct Chem. 75: 734-739. PMID: 31166927Niobium isocyanide complexes, Nb(CNAr)6, with Ar= 2,6-dimethylphenyl (Xyl), a diamagnetic dimer containing four reductively coupled isocyanides, and Ar= 2,6-diisopropylphenyl (Dipp), a paramagnetic monomer analogous to the highly unstable hexacarbonylniobium(0). | Kucera, BE., et al. 2019. Acta Crystallogr C Struct Chem. 75: 1259-1265. PMID: 31484814Homocoupling of CO and isocyanide mediated by a C,C′-bis(silylenyl)-substituted ortho-carborane. | Xiong, Y., et al. 2020. Chem Commun (Camb). 56: 747-750. PMID: 31845675An Isolable Three-Coordinate Germanone and Its Reactivity. | Zhao, XX., et al. 2021. Chemistry. 27: 15914-15917. PMID: 34529306Electronic Structure Analysis and Reactivity of the Bimetallic Bis-Titanocene Vinylcarboxylate Complex, [(Cp2Ti)2(O2C3TMS2)]. | Huh, DN., et al. 2021. Polyhedron. 207: PMID: 34824487Panchromatic Excited-State Absorption in Bis-Cyclometalated Iridium Isocyanide Complexes. | Olumba, ME., et al. 2022. Inorg Chem. 61: 19344-19353. PMID: 36383761
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