Product Name :
(+)-1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene (CAS 136705-65-2)
Synonym :
(R,R)-Isopropyl-DuPhos
Application :
CAS:
136705-65-2
Purity:
Molecular Weight:
418.58
Formula :
C26H44P2
Physical state:
Solid
solubility :
Shipping Condition :
Store at room temperature
Melting point:
40° C
SMILES:
CC(C)[C@H]1CC[C@@H](P1C2=CC=CC=C2P3[C@H](CC[C@@H]3C(C)C)C(C)C)C(C)C
References:
:Syntheses and Catalytic Hydrogenation Performance of Cationic Bis(phosphine) Cobalt(I) Diene and Arene Compounds. | Zhong, H., et al. 2019. Angew Chem Int Ed Engl. 58: 9194-9198. PMID: 31071227Three-Coordinate Formal Cobalt(0), Iron(0), and Manganese(0) Complexes with Persistent Carbene and Alkene Ligation. | Liu, Y., et al. 2020. Acc Chem Res. 53: 244-254. PMID: 31880150Cobalt-Catalyzed Asymmetric Hydrogenation of alpha , beta -Unsaturated Carboxylic Acids by Homolytic H2 Cleavage. | Zhong, H., et al. 2020. J Am Chem Soc. 142: 5272-5281. PMID: 32064867Ligand Substitution and Electronic Structure Studies of Bis(phosphine)Cobalt Cyclooctadiene Precatalysts for Alkene Hydrogenation. | Zhong, H., et al. 2021. Can J Chem. 99: 193-201. PMID: 34334799Mechanistic Investigations of the Asymmetric Hydrogenation of Enamides with Neutral Bis(phosphine) Cobalt Precatalysts. | Mendelsohn, LN., et al. 2022. J Am Chem Soc. 144: 15764-15778. PMID: 35951601
1608495-27-7 Purity 259214-55-6 site
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